Accuracy
trans (Me2S)2NiCl2 r
3600 trans (Me2S)2NiCl2 (Geo)
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REF: Estimated from DGauss results of DFT calculations, using the B88-PW91 functional and the DZVP basis set, in CAChe 6.0, Fujitsu Ltd, 2003.
UHF SHIFT=80 PM7
trans (Me2S)2NiCl2
<Ni-S> <><> <Ni-Cl> <Cl-Ni-S> GR=PW91D
Ni 0.00000000 +0 0.0000000 +0 0.0000000 +0 0 0 0
S 2.26066500 +1 0.0000000 +0 0.0000000 +0 1 0 0
S 2.26950986 +1 179.4190895 +1 180.0000000 +0 1 2 0
Cl 2.20419400 +1 87.4060890 +1 94.6431669 +1 1 2 3
Cl 2.26764916 +1 91.4337569 +1 178.6727512 +1 1 2 4
C 1.83566832 +1 108.4680675 +1 -52.8629422 +1 2 1 5
C 1.83568255 +1 108.0285668 +1 107.2906542 +1 2 1 6
C 1.83465295 +1 108.0003360 +1 128.7618986 +1 3 1 5
C 1.83467865 +1 107.6888510 +1 107.0037159 +1 3 1 8
H 1.09582458 +1 109.5283948 +1 -67.0044066 +1 6 2 1
H 1.09602031 +1 109.5186107 +1 67.2355801 +1 7 2 1
H 1.09981751 +1 113.3040323 +1 -120.1610033 +1 7 2 11
H 1.09484532 +1 110.6434784 +1 175.3878287 +1 8 3 1
H 1.09945343 +1 113.3146299 +1 -121.2644232 +1 8 3 13
H 1.09493722 +1 110.6731004 +1 -173.6674433 +1 9 3 1
H 1.09988751 +1 113.3051039 +1 120.0756271 +1 6 2 10
H 1.09936669 +1 113.3534216 +1 121.1802001 +1 9 3 15
H 1.09459162 +1 110.6745527 +1 121.1801625 +1 6 2 16
H 1.09471124 +1 110.6693932 +1 -121.1527664 +1 7 2 12
H 1.09633595 +1 109.6218123 +1 -120.0536700 +1 8 3 14
H 1.09658572 +1 109.5211796 +1 120.1568621 +1 9 3 17